2,4-Dichloro-N-[ethyl(2-hydroxyethyl)carbamothioyl]benzamide
نویسندگان
چکیده
In the title compound, C12H14Cl2N2O2S, the mol-ecule adopts a cis conformation with respect to the di-chloro-benzoyl group against the thiono group about the C-N bond. However, the di-chloro-benzene group and the thio-urea moiety are twisted by 75.41 (8)°. An intra-molecular N-H⋯O hydrogen bond occurs between the amido H atom and hydroxyl O atom. In the crystal, O-H⋯S and O-H⋯O hydrogen bonds link the molecules, forming chains along the b-axis direction.
منابع مشابه
N-[Ethyl(2-hydroxyethyl)carbamothioyl]-2-methylbenzamide
The title compound, C13H18N2O2S, adopts a cis conformation between the methyl-benzoyl and thiono groups across their thio-urea C-N bond. However, the methyl-benzoyl group and N2CS thio-urea moiety are twisted by 15.03 (3)°. In the molecule there is an N-H⋯O hydrogen bond. In the crystal, mol-ecules are linked by O-H⋯O inter-actions, generating chains extending along the c-axis direction.
متن کاملN-[Ethyl(2-hydroxyethyl)carbamothioyl]-3-fluorobenzamide
In the title compound, C12H15FN2O2S, the mol-ecule adopts a cis configuration of the fluoro-benzoyl group with respect to the thiono group about their C-N bond. The dihedral angle between the fluoro-benzoyl group and the thio-urea N2CS fragment is 69.60 (11)°. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules form chains along the b-axis direction via O-H⋯S and C-H⋯O hyd...
متن کامل(R)-N-[(R)-2,2-Dichloro-1-phenyl-2-(phenylsulfonyl)ethyl]-2-methylpropane-2-sulfinamide
The title mol-ecule, C18H21Cl2NO3S2, contains one chiral carbon center and the absolute sterochemistry has been confirmed as as R. An intra-molecular N-H⋯O hydrogen bond occurs and the dihedral angle between the benzene rings is 64.5 (1)°. In the crystal, the mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming a zigzag chain structure extending along the c-axis direction.
متن کاملN-{2-[4-(2-Hydroxyethyl)piperazin-1-yl]ethyl}phthalimide
In the title compound, C(16)H(21)N(3)O(3), the piperazine ring adopts a chair conformation, with its N-C bonds in pseudo-equatorial orientations. In the crystal, mol-ecules are linked by O-H⋯N hydrogen bonds, generating C(5) chains propagating in [101]. Weak aromatic π-π stacking inter-actions also occur [centroid-centroid separation = 3.899 (1) Å].
متن کاملCrystal structure of 4-methyl-N-[2-(piperidin-1-yl)ethyl]benzamide monohydrate
In the title compound, C15H22N2O·H2O, the dihedral angle between the planes of the piperidine and benzene rings is 31.63 (1)°. The piperidine ring adopts a chair conformation. The water solvent mol-ecule is involved in inter-species O-H⋯O, O-H⋯N, N-H⋯O and weak C-H⋯O hydrogen-bonding inter-actions, giving rise to chains extending along [010].
متن کامل